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Friday, February 25, 2011

CEMENT !!! Part I

By no means complicated , cement is simply a material to hold together materials !!!  Technically speaking , Cement is the generic name of all those materials which initially have plastic flow , but when it is mixed with water or any other suitable liquid , forms a rigid - continuous mixture which solidifies on standing and when solidified has the capability to resist high compressive strengths . 


The most common type of cement is PORTLAND CEMENT !!! Way back in 1824 , an Englishman named JOSEPH ASPDIN patented portland cement . He obtained it by the calcination of an argillaceous limestone . He named it PORTLAND as synonymous to a type of rock found at the Isle Of Portland ,  famous for it's strength . One to think that this was the start for mankind's construction glue :P is wrong , cause centuries ago Romans built the famous "Colosseum" using a cement like material called POZZOLANS !!! pretty impressive huh ;) 


Basically , Cement can be summerised as a mixture of finely ground calcium silicates and aluminates of varying compositions , which decide the properties of that particular variety of cement . The main constituents of cement can be summed up into four varieties :
1)  C2S
2)  C3S
3)  C3A
4)  C4AF
Where , 
C = CaO
S = SiO2
A = Al2O3
F = Fe2O3


Varying these % 's can lead to different types of Portland cements namely :- 


A ) TYPE - I :  REGULAR
      It has the following composition : 
      55% (C3S), 19% (C2S), 10% (C3A), 7% (C4AF), 2.8% MgO, 2.9% (SO3), 1.0% Ignition loss, 
      and 1.0% free CaO. 
      It is used for general construction purposes . It gains it's full strength in 28 days . 


B ) TYPE - II : MODIFIED 
      It has the following composition : 
      51% (C3S), 24% (C2S), 6% (C3A), 11% (C4AF), 2.9% MgO, 2.5% (SO3), 0.8% Ignition loss, 
      and 1.0% free CaO.
      The higher C2S composition makes the cement moderately sulfate resistant and also 
      it has a moderate heat- of-hydration value .
      It is used specifically in places where the sulfur content in the soil is high .   
 C)  TYPE - III : HIGH EARLY STRENGTH 
        It has the following composition : 
        57% (C3S), 19% (C2S), 10% (C3A), 7% (C4AF), 3.0% MgO, 3.1% (SO3), 0.9% Ignition loss, 
        and 1.3% free CaO.
        It has the ability to attain the strength of Type - I cement in just 3 days , but due 
       to the high % of C3S and C3A " together" can be devastating and can cause high 
       values of Heat-of-Hydration , thus long-time strength has to be sacrificed . Thus , it 
       is useless for massive construction works .
       Used only for emergency  constructions where we do not have much time to wait 
       for it to stand to gain strength .
  D) TYPE - IV : LOW HEAT 
        It has the following composition : 
      28% (C3S), 49% (C2S), 4% (C3A), 12% (C4AF), 1.8% MgO, 1.9% (SO3), 0.9% Ignition loss, 
      and 0.8% free CaO.
      Notice the lower % of C3S and C3A , which are the major contributors of heat-of-
      hydration . Consequently , the % of C4AF and other aggregates have to be increased.  
      Only drawback is that the time required to gain full strength is high when compared 
      to normal cement . 
      It is used for massive construction works like dams , etc .  


E ) TYPE - V : SULFATE RESISTANT 
       It has the following composition : 
     38% (C3S), 43% (C2S), 4% (C3A), 9% (C4AF), 1.9% MgO, 1.8% (SO3), 0.9% Ignition loss, 
     and 0.8% free CaO.
     This kind of cement has the highest % composition of C2S , thus making it highly 
     sulfate resistant .
     Used in places nearby to the sea , as it resists sea contact very well . 


Preparation of cement is a two step process ...The real game's still on......Keep logged into this site for an overview into it soon ;)